華東理工大學(xué)

華東理工大學(xué)化學(xué)與分子學(xué)院碩士研究生導(dǎo)師信息介紹：馬海燕

教授 博士，博士生導(dǎo)師

電話：＋86 21 64253519

Email：haiyanma@ecust.edu.cn

2001年獲華東理工大學(xué)應(yīng)用化學(xué)專業(yè)博士學(xué)位。于2001年5月赴德國留學(xué)深造，在烏爾姆大學(xué)Bernhard Rieger教授課題組進(jìn)行博士后研究。2002年6月至2003年9月獲德國洪堡基金會(huì)資助在德國美茵茲大學(xué)化學(xué)系Jun Okuda教授課題組做客座研究，后繼續(xù)于德國亞琛工業(yè)大學(xué)無機(jī)化學(xué)研究所Jun Okuda教授研究組從事博士后研究工作。2005年6月回國，被聘為華東理工大學(xué)教授。迄今已在國內(nèi)外核心學(xué)術(shù)期刊及國際會(huì)議上發(fā)表學(xué)術(shù)論文60余篇，被SCI收錄引用564次，他引近500余次，單篇最高被引110余次。所參與科研項(xiàng)目“新型高效、高選擇性茂鈦?zhàn)褰饘俅呋瘎┑姆肿釉O(shè)計(jì)、合成及催化行為研究”獲2004年上海市科技進(jìn)步二等獎(jiǎng)（第四完成人）。2006年獲上海市科技啟明星計(jì)劃、教育部新世紀(jì)優(yōu)秀人才支持計(jì)劃支持。完成及承擔(dān)多項(xiàng)國家自然科學(xué)基金項(xiàng)目及省部級(jí)科研項(xiàng)目。現(xiàn)招收有機(jī)化學(xué)專業(yè)的碩士、博士研究生，以及工業(yè)催化專業(yè)的博士研究生。

目前承擔(dān)科研項(xiàng)目：

1）國家自然科學(xué)基金項(xiàng)目：分子內(nèi)陰陽離子型鈣、鎂、鋅絡(luò)合物催化丙交酯立體選擇性聚合研究（2011.1.1～2012.12.30，總經(jīng)費(fèi)37萬）

2）國家自然科學(xué)基金項(xiàng)目：橋聯(lián)茚-芴鈦?zhàn)褰j(luò)合物催化丙烯高選擇性二聚研究（2013.1.1～2016.12.31，總經(jīng)費(fèi)78萬）

主要研究方向

1）新型過渡金屬絡(luò)合物的設(shè)計(jì)合成及應(yīng)用于催化制備結(jié)構(gòu)可控高性能聚烯烴。

設(shè)計(jì)及合成各種結(jié)構(gòu)類型的過渡金屬有機(jī)化合物作為烯烴聚合催化劑。通過分子水平的催化劑結(jié)構(gòu)設(shè)計(jì)來實(shí)現(xiàn)烯烴聚合、齊聚過程，聚烯烴結(jié)構(gòu)的可控、可調(diào)（分子量，分子量分布，共聚單體分布，支化度，聚合物鏈立體規(guī)整性等），以獲得各種新型結(jié)構(gòu)可控高性能聚烯烴材料。

2）新型主族及過渡金屬絡(luò)合物的設(shè)計(jì)合成及催化制備綠色環(huán)境友好聚合物材料的應(yīng)用。
設(shè)計(jì)合成新型結(jié)構(gòu)金屬催化劑如稀土、鋁、鈣、鎂等金屬的絡(luò)合物用于催化內(nèi)酯等開環(huán)聚合。通過分子水平的催化劑結(jié)構(gòu)設(shè)計(jì)、調(diào)控來實(shí)現(xiàn)對(duì)聚合物立體規(guī)整性、鏈結(jié)構(gòu)的有序控制，獲得新型結(jié)構(gòu)可控環(huán)境友好聚酯材料。

代表性論文：

1.Yuan Wang, Haiyan Ma*, “Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and L-lactide”, Chem. Commun., 2012, 48, 6729-6731.

2.Shaodi Song, Xingyu Zhang, Haiyan Ma*, Yang Yang, “Zinc complexes supported by claw-type aminophenolate ligands: synthesis, characterization and catalysis in the ring-opening polymerization of rac-lactide”, Dalton Trans., 2012, 41, 3266-3277.

3.Liying Wang, Haiyan Ma*, “Highly Active Magnesium Initiators for Ring-Opening Polymerization of rac-Lactide”, Macromolecules, 2010, 43, 6535-6537.

4.Liying Wang, Haiyan Ma*, “Zinc complexes supported by multidentate amino-phenolate ligands: synthesis, structure and catalysis in ring-opening polymerization of rac-lactide”, Dalton Trans., 2010, 39, 7897-7910.

5.Feng Qian, Keyin Liu, Haiyan Ma*, “Amidinate aluminum complexes: synthesis, characterization and ring-opening polymerization of rac-lactide”, Dalton Trans., 2010, 39, 8071-8083.

6.Shaogang Gong, Haiyan Ma*, Jiling Huang*, “Zirconium and hafnium complexes supported by linked bis(beta-diketiminate) ligands: synthesis, characterization and catalytic application in ethylene polymerization”, Dalton Trans., 2009, 8237-8247.

7.Bing Lian, Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Neutral and cationic aluminium complexes containing a chiral (OSSO)-type bis(phenolato) ligand: synthesis, structures and polymerization activity”, Dalton Trans., 2009, 9033-9042.

8.Shaogang Gong, Haiyan Ma*, Jiling Huang*, “Zirconium Complexes with Versatile β-Diketiminate Ligands: Synthesis, Structure, and Ethylene Polymerization”, J. Organomet. Chem., 2008, 693, 3509-3518.

9.Shaogang Gong, Haiyan Ma*, “-Diketiminate aluminium complexes: synthesis, characterization and ring-opening polymerization of cyclic esters”, Dalton Trans., 2008, 3345-3357.

10.Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Rare-Earth Metal Complexes Supported by 1,ω-Dithiaalkanediyl-Bridged Bis(phenolato) Ligands: Synthesis, Structure, and Heteroselective Ring-Opening Polymerization of rac-Lactide”, Inorg. Chem. 2008, 47, 3328-3339.

11.Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato) scandium complexes”, Angew. Chem. Int. Ed. Engl. 2006, 46, 7818-7821 (VIP article).

12.Haiyan Ma, Jun Okuda, “Kinetics and mechanism of L-lactide polymerization by rare earth metal silylamido complexes: the effect of alcohol addition”, Macromolecules, 2005, 38, 2665-2673.

13.Haiyan Ma, Gianluca Melillo, Leone Oliva, Thomas P. Spaniol, Ulli Englert, Jun Okuda, “Living polymerization of racemic lactide by aluminum initiators supported by tetradentate OSSO ligands”, Dalton Trans., 2005, 721-727.

14.Wigand Braune, Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Aluminum complexes with sulfide-linked bis(phenolato) ligands: the unusual structure and reactivity of the methyl bis(phenolato) complex [Al(tbmp)Me] (tbmp= 2, 2’-thiobis(6-tert-4-methylphenolato))”, Organometallics, 2005, 24, 1953-1958.

15.Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Rare earth metal complexes supported by 1, -dithiaalkanediyl-bridged bis(phenolato) ligands: synthesis, characterization and ring-opening polymerization catalysis of L-lactide”, Dalton Trans., 2003, 4770-4780.